UK study: Autoclaving municipal waste can improve biogas yields by 300%

Pretreating municipal solid waste (MSW) in an autoclave before sending it to anaerobic digestion (AD) could increase methane generation by over 300% and substantially reduce the amount of material requiring disposal, research by Aerothermal Group says.

As part of the research, Dr. Zhengjian Wang and Dr. Nigel Baily conducted experiments in triplicate on two waste streams at Aerothermal’s test facility in Poole, UK.

The first waste stream consisted of a sample of MSW feedstock with large items removed.

Tests on this stream demonstrated how much extra material can go to the AD system as well as the increased gas yield per tonne of material fed to the system.

The second waste stream was a sample of MSW feedstock used to demonstrate the improvements that autoclaving can achieve on a like-for-like basis.  

The two waste samples were each divided into four portions, with one portion of each waste processed each day, four days per week.

One half of each portion was processed via the autoclave route and the other half was processed via a non-autoclave route.  

After loading, the autoclave was initially evacuated using a vacuum pump to remove incondensable gases, which were filtered out in activated carbon filter beds.

The autoclave was then brought up to pressure and temperature (6.2 bars abs/160°C) by the injection of steam, and when the temperature had equalised throughout the autoclave the load was left to ‘cook’ for 45 minutes.

Twelve constantly stirred cylindrical tank digesters, each of which has a working volume of 1.8l, were used for this trial.

To start the process, 1.8l of seed inoculums was first added into each digester, and when the digesters reached the required temperatures, a daily semi-continuous feeding regime was started according to defined organic loading rates.

A weekly composite digestate sample for each single digester was collected and the properties such as DS, VS, ammonia, and VFAs were analysed once per week.

Test results on the first waste stream (where large items had been removed) revealed that autoclaving gives a gas yield of about 150m3/tonne which is more than double the target of 65m3/tonne of waste.

Autoclaving also greatly increased the fraction of the waste that could be digested, as well as the gas yield from each kg of waste sent to the digesters which substantially reduced the amount of material requiring disposal.

Tests on the second (like-for-like) waste stream revealed that autoclaving gives a substantial improvement in gas yield, achieving again a figure in excess of 150m3/tonne of waste processed with a HRT of 27 days.

Both waste streams showed autoclaved materials were less susceptible to the development of high VFA concentrations than un-autoclaved material and steam consumption was in close agreement with predictions.

Christian Toll, AeroThermal’s CEO, says: ‘Now that we’ve got the scientific proof, we’re looking forward to working with waste disposal companies across the UK and beyond to help them use autoclaves to improve the way they dispose of their waste.’

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