Danish university research receives funding to produce hydrogen from biogas

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Denmark's first plant to produce hydrogen by catalytic pyrolysis of biogas is due to be ready in three years. The technology can convert carbon - captured via photosynthesis - into solid form and simultaneously produce hydrogen very energy-efficiently
Carbon capture and storage are necessary if the world is to have any chance at all of reaching the 1.5° C target in the Paris Agreement. And plants are already very good at capturing CO2 from the atmosphere, according to a new research project being conducted at Aarhus University.
The project will see the development of Denmark's first reactor to produce hydrogen from biogas using catalytic pyrolysis. In the pyrolysis process, high temperature is applied to split the methane in natural gas, or in renewable biogas, into hydrogen and carbon. The project is funded by the Independent Research Fund Denmark.
"What we need right now is not just zero carbon technologies. We also need carbon sequestering technologies with net negative carbon emissions. What we propose with this project is to adapt and optimise existing so-called turquoise hydrogen technology for biogas instead of natural gas. The result will be a genuine carbon-negative technology that is well-suited to Denmark's leading role as a biogas nation," said Associate Professor Patrick Biller from the Department of Biological and Chemical Engineering, who is heading the project.
Approximately 3% of global carbon emissions derive from the production of grey hydrogen, which is produced from natural gas. The general alternative to this is green hydrogen, by which water is split into hydrogen and oxygen through electrolysis.
However, green hydrogen production is at best carbon-neutral if renewable electricity is used, but never carbon-negative. It requires large amounts of energy to split water and if renewable energy is not used, the production emits CO2.
Currently 95% of global hydrogen production comes from the Steam Methane Reforming (SMR) process where natural gas is converted to hydrogen and CO2. Turquoise hydrogen is increasingly being investigated as an alternative; it also involves the production of hydrogen from natural gas, but pyrolysis is applied to convert the carbon into solid form. Normal turquoise hydrogen is carbon-neutral, as the carbon originates from natural gas and thus fossil resources, but it is not emitted into the atmosphere.
Biller proposes designing and developing a technology that produces turquoise hydrogen from biogas: "Plants perform carbon capture every day through photosynthesis, and they actually do so quite well. Biogas originates from plant material that has absorbed CO2 from the atmosphere in this way. This means that in biogas pyrolysis, carbon originally from the atmosphere is converted into solid form; a black powder that is pure carbon, and can either be deposited or used in industry for other high-value products," he said.
This means there are no carbon emissions, but a net negative contribution to the atmosphere, he added.
With the grant from Independent Research Fund Denmark, the research team now aims to design and develop a system that can manage the process. It is no small task, even though the aim is to adapt existing turquoise hydrogen technology.
"There’s a big difference between natural gas and biogas, for example there are a lot of very different impurities in biogas to take into account. At the same time, methane pyrolysis requires high temperatures of around 1200 degrees Celsius. We want to avoid this, so we will try and find metallic catalysts that can significantly reduce the amount of energy required to initiate the reaction. We expect to be able to run the reaction at temperatures around 500 - 600 degrees," said Biller.
The finished system is expected to be able to produce hydrogen using approximately one-fifth of the energy used in green hydrogen production. There is also the advantage in that this method binds carbon that originates from the atmosphere. The system will be tested and run at Aarhus University's research centre in Foulum, AU Viborg.
"Denmark has a world-leading biogas sector. We’re doing great things within Power-2-X and hydrogen, and we have an energy system with large amounts of renewable energy. Turquoise hydrogen from biogas fits into this mix perfectly, and I can see great perspectives for Denmark in this area in the future," concluded Biller.

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